1943: Albert Hofmann accidentally discovers the psychedelic properties of LSD.From Wired:
Hofmann, a Swiss chemist, was researching the synthesis of a lysergic acid compound, LSD-25, when he inadvertently absorbed a bit through his fingertips. Intrigued by the stimulating effects on his perception, Hofmann decided further exploration was warranted. Three days later he ingested 250 micrograms of LSD, embarking on the first full-fledged acid trip.
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